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Mumtaz Qazilbash, William & Mary Physics, Title of Talk: Recent insights into the metal-insulator transition of vanadium dioxide (VO₂) 

Abstract:
Metal-insulator transitions are among the most fascinating and least understood phenomena in condensed matter physics. Metal-insulator transitions lead to significant changes in the electronic conductivity and optical properties, and are generally accompanied by structural and magnetic transformations due to a complex interplay between charge, spin, orbital, and lattice degrees of freedom. The thermally-driven metal-insulator transition (MIT) in bulk vanadium dioxide (VO₂) is accompanied by a structural distortion that leads to pairing of all the vanadium atoms in the insulating phase. This V-V pairing has long been thought critical to the emergence of insulating behavior. We shall present our latest experiments on ultrathin VO₂ films grown on TiO₂ substrates. We demonstrate that the MIT in ultrathin VO₂ films occurs without the V-V structural distortion. Our results establish a route to a purely electronic MIT that is driven by electron-electron interactions. We shall also present our recent experiments and results on infrared nano-imaging and nano-spectroscopy of VO₂ films. The development of table-top, broadband infrared light sources in my lab has enabled nano-spectroscopy experiments on VO₂ and other materials.

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